Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

基于监测数据的全国地下水质动态变化特征     

殷秀兰  李圣品 《地质学报》2021,95(5):1356-1365

地下水质动态变化及其趋势研判是区域水资源调配决策的重要依据.本文以全国2007～2017年国家级地下水监测网水质数据为基础,结合典型地区的代表性监测组分超标特征及动态趋势,开展了地下水质动态变化过程研究,结果表明:全国地下水监测中以Ⅳ类水质点占比最大,其次为Ⅱ类水质点;Ⅰ～Ⅲ类水质点数量较少,而且占比以降低为主,Ⅳ和Ⅴ类地下水监测点逐渐增加,其中Ⅳ类水质点的比例由40.50％增加至51.45％;全国地下水质主要的超标组分为pH、总硬度、总溶解性固体、硫酸盐、氯化物、高锰酸钾指数、铁、锰、氟化物、"三氮".以华北地区、华东地区、西南地区和西北地区为代表,分析研究典型地区地下水质的动态变化过程及其影响因素,结果显示,在地下水位变化较大的地区,地下水质状况随着地下水位变化明显,在地下水位波动较小的地区,地下水质状况也基本上变化较小.研究成果对于科学评价地下水资源、合理制定区域地下水开发利用规划、防治地下水污染等具有一定的指导作用.  相似文献   

黑龙江省海伦市长发镇土地质量地球化学评价及开发建议     

刘国栋  杨泽  戴慧敏  张一鹤  肖红叶  陈江 《地质与资源》2021,29(6):533-542

  相似文献   

Microplastic pollution in surface water and sediments of Qinghai-Tibet Plateau: Current status and causes     

《China Geology》2021,4(1):178-184

To study the current status and causes of the microplastic pollution in surface water of the Qinghai-Tibet Plateau, this paper compared the average microplastic abundance in sediments and surface water of the Qinghai-Tibet Plateau and the results are as follows. First, the average microplastic abundance in surface water of the independent rivers and the whole area is 247–2686 items/m³ and 856 items/m³, respectively. The average microplastic abundance in sediments of independent rivers or lakes and the whole area is 0–933 items/m² and 362 items/m², respectively. Meanwhile, the degree of microplastic pollution in river sediments is higher than that in lake sediments, and the rivers suffering from microplastic pollution mainly include the Brahmaputra River, Tongtian River, and Nujiang River. Second, compared with the microplastic pollution in other areas of the world, the levelof microplastic pollution in the lakes and rivers of the Qinghai-Tibet plateau is not lower than that of well-developed areas with more intensive human activities. Finally, this study suggests that relevant government departments of the Qinghai-Tibet Plateau should strengthen waste management strategies while developing tourism and that much attention should be paid to the impacts of microplastics in the water environment.©2021 China Geology Editorial Office.  相似文献   

Sensitivity assessment of strontium isotope as indicator of polluted groundwater for hydraulic fracturing flowback fluids produced in the Dameigou Shale of Qaidam Basin          下载免费PDF全文

Zheng Zhao-xian  Cui Xiao-shun  Zhu Pu-cheng  Guo Si-jia 《地下水科学与工程》2021,9(2):93-101

Hydrogeochemical processes that would occur in polluted groundwater and aquifer system, may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF) in groundwater. In this paper, the Dameigou shale gas field in the northern Qaidam Basin was taken as the study area, where the hydrogeochemical processes affecting Sr isotope was analysed. Then, the model for Sr isotope in HFFF-polluted groundwater was constructed to assess the sensitivity of Sr isotope as HFFF indicator. The results show that the dissolution can release little Sr to polluted groundwater and cannot affect the εSr(the deviation of the 87 Sr/86 Sr ratio) of polluted groundwater. In the meantime, cation exchange can considerably affect Sr composition in the polluted groundwater. The Sr with low εSr is constantly released to groundwater from the solid phase of aquifer media by cation exchange with pollution of Quaternary groundwater by the HFFF and it accounts for 4.6% and 11.0% of Sr in polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. However, the Sr from cation exchange has limited impact on Sr isotope in polluted groundwater. Addition of Sr from cation exchange would only cause a 0.2% and 1.2% decrease in εSr of the polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. These results demonstrate that hydrogeochemical processes have little effect on the sensitivity of Sr isotope being the HFFF indicator in groundwater of the study area. For the scenario of groundwater pollution by HFFF, when the HFFF accounts for 5%(in volume percentage) of the polluted groundwater, the HFFF can result in detectable shifts of εSr(ΔεSr=0.86) in natural groundwater. Therefore, after consideration of hydrogeochemical processes occurred in aquifer with input of the HFFF, Sr isotope is still a sensitive indicator of the Quaternary groundwater pollution by the HFFF produced in the Dameigou shale of Qaidam Basin.  相似文献   

基于最优概率的中期延伸期过程累计降水量分级订正预报     

牛若芸 《热带气象学报》2019,35(6):721-731

采用ECMWF集合预报降水量资料和中国降水量观测资料,研发了基于最优概率的过程累计降水量分级订正预报(OPPF)技术,并在遵循总体技术思路的基础上设计出三种不同的OPPF计算方案(OPPF1、OPPF2、OPPF3),继而选用2015—2017年汛期(5—9月)中国91次区域性强降水过程进行回报试验和预报效果对比评估,结果表明:(1)在中期延伸期预报时效(96~360小时),对强降水和有无降水的预报效果,三种OPPF均明显优于集合平均(EMPF)和控制预报(CTPF);对中等以上或较强以上强度降水的预报效果,OPPF1和OPPF3明显优于CTPF、与EMPF基本接近。(2)三种OPPF相比,OPPF3的预报效果较OPPF1总体略胜一筹,两者均好于OPPF2。(3)预报效果存在明显的地域差异,南方地区强降水预报的TS评分明显大于北方地区,且OPPF3预报效果明显优于EMPF;在96~240小时预报时效,东北地区东部OPPF3强降水的预报效果也明显好于EMPF。   相似文献   

太原汛期短时强降水环流分型及环境参量分析     

周晋红  赵彩萍  董春卿 《干旱气象》2019,37(3):392-399

应用太原1996-2015年7个国家气象站、2008-2015年63个区域站6-9月逐时降水资料及相关探空、地面观测资料,对太原短时强降水日环流配置进行天气学分型,分析各流型下关键环境参数分布特征。结果表明,太原发生短时强降水的500 hPa环流形势有四种:冷涡型、高空槽型、高空槽加副高型、西北气流型。太原短时强降水常发生在比较温和的对流有效位能(CAPE)环境下,大部分过程CAPE值≤1500 J·kg^-1,冷涡型则≤1000 J·kg^-1。西北气流型850 hPa与500 hPa温差(ΔT850-500)大,静力不稳定度比其他型更强,且500 hPa有明显的干层存在。高空槽加副高型K指数大,且暖云厚度均值达3576 m,明显大于其他型2471~2608 m的均值。冷涡型全部、高空槽型85%的过程出现在弱0~6 km垂直风切变环境下,而高空槽加副高型、西北气流型0~6 km垂直风切变相对较大,35%以上达到中等强度。冷涡型、西北气流型短时强降水太原上空700 hPa水汽常比850 hPa更充沛。太原超过70 mm·h^-1的极端降水出现在西北气流型下,有中等强度的CAPE值、强层结不稳定、弱0~6 km垂直风切变、3550 m以上暖云厚度,中低空水汽充足,这些环境参量的配合对强降水效率有很好的指示意义。  相似文献   

北京“623”大暴雨的强降水超级单体特征和成因研究     

张文龙  崔晓鹏  黄荣  黎慧琦 《大气科学》2019,43(5):1171-1190

本文利用雷达、加密地面自动站等高时空分辨率的观测资料,结合NCEP 1°×1°再分析资料、常规观测等资料,对2011年6月23日发生在北京城区的极端强降水事件开展了细致的观测和诊断分析。结果表明,这次极端强降水事件,主要是由向东南移动的东北—西南走向的飑线右端的强降水超级单体（High Precipitation Supercell,简称HPS）造成的,这是目前已有文献记载的中国发生纬度最高的HPS。HPS在移动方向的右后侧和右前侧均有明显的“V”型入流,这不同于已有HPS模型,表明中、低层干冷空气和低层暖湿气流特征显著。在环境条件方面,存在对流层低层逆温层,其能量存储盖作用使得雷暴具有爆发性增强的潜势,但该逆温层是在08:00～14:00（北京时,下同）的6小时内形成的,对业务预报极具挑战性。相对其他大气层结热动力参数, 风暴相对螺旋度和粗理查逊数在14:00较08:00显著增大,对HPS的发生具有一定指示作用。高空偏西风急流和低层偏东风活动显著,使得北京地区的水平风垂直切变增强,形成上干下湿的对流不稳定以及次级环流圈。高空急流造成强烈的相当位温差动平流,促进对流不稳定度发展加强。结合复杂地形作用,在北京西部100 m地形高度线附近形成显著的平原暖湿空气与山地干冷空气的干湿分界线以及风场辐合线。水汽供应主要源自低层偏东风和本地水汽积累。当飑线从西北方向侵入北京并向东南方向移动时,在北部山区,由于条件不足,雷暴没有显著发展加强;然而,在西部山区,在湖面、城市热岛、低层偏东风、冷池出流共同作用下,加之其他有利的环境条件,飑线右端雷暴强烈发展加强,特别是当经过100 m地形高度线附近时发展成为HPS,进而造成石景山区模式口站的大暴雨中心。  相似文献   

苏州市一次重霾污染天气过程的数值模拟   总被引：1，自引：1，他引：0  

吴珂  包云轩  蔡敏  金建平  牛利  严明良 《气象科学》2019,39(1):104-116

本文对苏州地区2015年12月13—15日发生的一次典型的重霾污染天气过程进行了数值模拟,分析了颗粒物及其组分的时空变化特征及其气象影响因子,以期为该区域空气污染治理和预防提供科学依据。结果表明:(1)利用WRF-Chem模式对此次重霾污染天气过程的污染气体成分进行数值模拟后发现,小时平均的PM_(2.5)、PM_(10)、CO、SO_2、NO_2模拟值与实测值的相关系数较高,达到0.68以上,通过了P0.01的显著性检验,且日变化过程对应也较好。(2)通过分析此次污染过程的天气背景,发现污染形成期高空环流比较平直,中层为均匀的弱高压控制,地面受弱高压脊控制,这种形势容易导致颗粒物的堆积。后期地面等压线密集时,风速大,有利于污染物的输送与扩散。(3)通过分析此次污染过程期间气象要素的变化发现,有逆温、风速小、相对湿度大等不利的气象条件是导致此次污染过程发生的重要原因之一。(4)HYSPLIT轨迹分析显示,此次重霾过程主要受北方大范围灰霾颗粒物南下影响,北方污染气团逐步南推,14至15日本地大气扩散条件差、污染物累积,最终导致本地污染加重,从而发生重霾事件。(5)火点图的分布进一步验证了此次重霾污染过程是由外来污染气团输入所导致。  相似文献   

2017年江西汛期设区市城区暴雨回波特征分析   总被引：3，自引：3，他引：0  

邓虹霞  智海  马中元  张瑛  何文 《气象科学》2019,39(2):274-284

使用江西WebGIS雷达拼图和自动站雨量、雷电监测、强天气监测等数据,以及MICAPS常规天气图资料,对2017年3—7月江西汛期11个设区市26次城区暴雨过程的雷达回波特征进行分析。结果表明:2017年江西汛期共出现52日暴雨过程,其中江西11个设区市所在地城区出现26次暴雨。在这26次城区暴雨个例中,有23次伴随出现短时强降水,有3次降水比较均匀。暴雨维持时间长短不一,最长的有15 h,最短只有3 h,平均是10 h。有5次出现大风天气,21次没有大风出现。雷达回波特征主要有3种:块状(强单体、超级单体)、带状(飑线、回波带)、絮状(絮带、絮团)。这3种回波形态特征,出现率最高的是絮状回波,即比较宽、嵌有中等强度的对流单体絮带状回波带,强度40～55 dBz,出现16次,概率62%;其次是窄而长、紧密排列由强单体组成的飑线回波带,强度50～60 dBz,出现8次,概率30%;块状(强单体、超级单体)回波强度最强,中心强度达到60～70 dBz,出现2次,概率8%。  相似文献